2014 Singles - Main
1/16-finals
| 1 | Raonic M. (1) | Bye | |
| 2 | Berankis R. (Q) | Karatsev A. (Q) | 2 : 0 |
| 3 | Groth S. | Rublev A. (WC) | 2 : 0 |
| 4 | Kuznetsov An. | Bautista-Agut R. (5) | 0 : 2 |
| 5 | Gulbis E. (3) | Bye | |
| 6 | Vesely J. | Gimeno-Traver D. | 0 : 2 |
| 7 | Dodig I. | Riba P. | 2 : 0 |
| 8 | Lajovic D. | Seppi A. (8) | 0 : 2 |
| 9 | Youzhny M. (7) | Baluda V. (Q) | 2 : 0 |
| 10 | Lorenzi P. | Monaco J. | 1 : 2 |
| 11 | Kukushkin M. | Khachanov K. (WC) | 2 : 1 |
| 12 | Bye | Fognini F. (4) | |
| 13 | Robredo T. (6) | Krstin P. (Q) | 2 : 0 |
| 14 | Jaziri M. | Krajinovic F. | 0 : 2 |
| 15 | Sela D. | Donskoy E. (WC) | 0 : 2 |
| 16 | Bye | Cilic M. (2) |
1/8-finals
Quarter-finals
| 1 | Berankis R. | Bautista-Agut R. (5) | 0 : 2 |
| 2 | Gulbis E. (3) | Seppi A. (8) | 2 : 1 |
| 3 | Youzhny M. (7) | Kukushkin M. | 1 : 2 |
| 4 | Robredo T. (6) | Cilic M. (2) | 0 : 2 |
Semi-finals
| 1 | Bautista-Agut R. (5) | Gulbis E. (3) | 2 : 0 |
| 2 | Kukushkin M. | Cilic M. (2) | 1 : 2 |
Final
| 1 | Bautista-Agut R. (5) | Cilic M. (2) | 0 : 2 |
2014 Singles - Qualification
Quarter-finals
| 1 | Dzumhur D. (1) | Bublik A. (WC) | 2 : 1 |
| 2 | Cervantes I. | Baluda V. | 0 : 2 |
| 3 | Lobkov A. (RET.) | Matsukevitch D. | 0 : 0 |
| 4 | Vagnozzi S. | Molchanov D. (6) | 2 : 1 |
| 5 | Berankis R. (2) | Zaitcev A. | 2 : 0 |
| 6 | Davydenko P. | Vasilenko A. | 2 : 1 |
| 7 | Vatutin A. | Kravchuk K. | 0 : 2 |
| 8 | Koniusz B. | Marchenko I. (5) | 0 : 2 |
| 9 | Pavic A. (3) | Krstin P. | 0 : 2 |
| 10 | Cacic N. | Gerasimov E. | 0 : 2 |
| 11 | Shyla Y. | Polyakov V. (WC) | 2 : 0 |
| 12 | Korolev E. | Albot R. (7) | 0 : 2 |
| 13 | Pouille L. (4) | Alekseenko V. | 2 : 0 |
| 14 | Muzaev R. | Karlovskiy E. (WC) | 1 : 2 |
| 15 | Ledovskikh M. | Medvedev D. (WC) | 0 : 2 |
| 16 | Karatsev A. | Basilashvili N. (8) | 2 : 0 |
Semi-finals
Final
| 1 | Baluda V. | Matsukevitch D. | 2 : 1 |
| 2 | Berankis R. (2) | Kravchuk K. | 2 : 0 |
| 3 | Krstin P. | Shyla Y. | 2 : 1 |
| 4 | Pouille L. (4) | Karatsev A. | 0 : 2 |
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